[ee60aa7] | 1 | // TODO: interface to form_volume/shell_volume not yet settled |
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[d86f0fc] | 2 | static double |
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[ee60aa7] | 3 | shell_volume(double *total, double length_a, double b2a_ratio, double c2a_ratio, double thickness) |
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[deb7ee0] | 4 | { |
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[ab2aea8] | 5 | double length_b = length_a * b2a_ratio; |
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| 6 | double length_c = length_a * c2a_ratio; |
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[a807206] | 7 | double a_core = length_a - 2.0*thickness; |
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[ab2aea8] | 8 | double b_core = length_b - 2.0*thickness; |
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| 9 | double c_core = length_c - 2.0*thickness; |
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[deb7ee0] | 10 | double vol_core = a_core * b_core * c_core; |
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[ee60aa7] | 11 | *total = length_a * length_b * length_c; |
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| 12 | return *total - vol_core; |
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| 13 | } |
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| 14 | |
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| 15 | static double |
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| 16 | form_volume(double length_a, double b2a_ratio, double c2a_ratio, double thickness) |
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| 17 | { |
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| 18 | double total; |
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| 19 | return shell_volume(&total, length_a, b2a_ratio, c2a_ratio, thickness); |
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[deb7ee0] | 20 | } |
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| 21 | |
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[d277229] | 22 | static double |
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| 23 | effective_radius(int mode, double length_a, double b2a_ratio, double c2a_ratio, double thickness) |
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[a94046f] | 24 | //effective_radius_type = ["equivalent sphere","half length_a", "half length_b", "half length_c", |
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| 25 | // "equivalent outer circular cross-section","half ab diagonal","half diagonal"] |
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| 26 | // NOTE length_a is external dimension! |
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[d277229] | 27 | { |
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[ee60aa7] | 28 | switch (mode) { |
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| 29 | case 1: // equivalent sphere |
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[d277229] | 30 | return cbrt(0.75*cube(length_a)*b2a_ratio*c2a_ratio/M_PI); |
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[ee60aa7] | 31 | case 2: // half length_a |
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[d277229] | 32 | return 0.5 * length_a; |
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[ee60aa7] | 33 | case 3: // half length_b |
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[d277229] | 34 | return 0.5 * length_a*b2a_ratio; |
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[ee60aa7] | 35 | case 4: // half length_c |
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[d277229] | 36 | return 0.5 * length_a*c2a_ratio; |
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[ee60aa7] | 37 | case 5: // equivalent outer circular cross-section |
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[d277229] | 38 | return length_a*sqrt(b2a_ratio/M_PI); |
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[ee60aa7] | 39 | case 6: // half ab diagonal |
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[d277229] | 40 | return 0.5*sqrt(square(length_a) * (1.0 + square(b2a_ratio))); |
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[ee60aa7] | 41 | case 7: // half diagonal |
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[d277229] | 42 | return 0.5*sqrt(square(length_a) * (1.0 + square(b2a_ratio) + square(c2a_ratio))); |
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| 43 | } |
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| 44 | } |
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| 45 | |
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[71b751d] | 46 | static void |
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| 47 | Fq(double q, |
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| 48 | double *F1, |
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| 49 | double *F2, |
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[deb7ee0] | 50 | double sld, |
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| 51 | double solvent_sld, |
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[a807206] | 52 | double length_a, |
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[deb7ee0] | 53 | double b2a_ratio, |
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| 54 | double c2a_ratio, |
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| 55 | double thickness) |
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| 56 | { |
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[6f676fb] | 57 | const double length_b = length_a * b2a_ratio; |
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| 58 | const double length_c = length_a * c2a_ratio; |
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| 59 | const double a_half = 0.5 * length_a; |
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| 60 | const double b_half = 0.5 * length_b; |
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| 61 | const double c_half = 0.5 * length_c; |
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| 62 | const double vol_total = length_a * length_b * length_c; |
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| 63 | const double vol_core = 8.0 * (a_half-thickness) * (b_half-thickness) * (c_half-thickness); |
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[deb7ee0] | 64 | |
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[ab2aea8] | 65 | //Integration limits to use in Gaussian quadrature |
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[6f676fb] | 66 | const double v1a = 0.0; |
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| 67 | const double v1b = M_PI_2; //theta integration limits |
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| 68 | const double v2a = 0.0; |
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| 69 | const double v2b = M_PI_2; //phi integration limits |
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[8de1477] | 70 | |
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[71b751d] | 71 | double outer_sum_F1 = 0.0; |
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| 72 | double outer_sum_F2 = 0.0; |
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[74768cb] | 73 | for(int i=0; i<GAUSS_N; i++) { |
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[deb7ee0] | 74 | |
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[74768cb] | 75 | const double theta = 0.5 * ( GAUSS_Z[i]*(v1b-v1a) + v1a + v1b ); |
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[6f676fb] | 76 | double sin_theta, cos_theta; |
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| 77 | SINCOS(theta, sin_theta, cos_theta); |
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[deb7ee0] | 78 | |
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[1e7b0db0] | 79 | const double termC1 = sas_sinx_x(q * c_half * cos(theta)); |
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| 80 | const double termC2 = sas_sinx_x(q * (c_half-thickness)*cos(theta)); |
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[deb7ee0] | 81 | |
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[71b751d] | 82 | double inner_sum_F1 = 0.0; |
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| 83 | double inner_sum_F2 = 0.0; |
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[74768cb] | 84 | for(int j=0; j<GAUSS_N; j++) { |
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[deb7ee0] | 85 | |
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[74768cb] | 86 | const double phi = 0.5 * ( GAUSS_Z[j]*(v2b-v2a) + v2a + v2b ); |
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[6f676fb] | 87 | double sin_phi, cos_phi; |
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| 88 | SINCOS(phi, sin_phi, cos_phi); |
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[deb7ee0] | 89 | |
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| 90 | // Amplitude AP from eqn. (13), rewritten to avoid round-off effects when arg=0 |
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| 91 | |
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[1e7b0db0] | 92 | const double termA1 = sas_sinx_x(q * a_half * sin_theta * sin_phi); |
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| 93 | const double termA2 = sas_sinx_x(q * (a_half-thickness) * sin_theta * sin_phi); |
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[deb7ee0] | 94 | |
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[1e7b0db0] | 95 | const double termB1 = sas_sinx_x(q * b_half * sin_theta * cos_phi); |
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| 96 | const double termB2 = sas_sinx_x(q * (b_half-thickness) * sin_theta * cos_phi); |
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[deb7ee0] | 97 | |
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[6f676fb] | 98 | const double AP1 = vol_total * termA1 * termB1 * termC1; |
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| 99 | const double AP2 = vol_core * termA2 * termB2 * termC2; |
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[deb7ee0] | 100 | |
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[71b751d] | 101 | inner_sum_F1 += GAUSS_W[j] * (AP1-AP2); |
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| 102 | inner_sum_F2 += GAUSS_W[j] * square(AP1-AP2); |
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[ab2aea8] | 103 | } |
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[71b751d] | 104 | inner_sum_F1 *= 0.5 * (v2b-v2a); |
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| 105 | inner_sum_F2 *= 0.5 * (v2b-v2a); |
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[deb7ee0] | 106 | |
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[71b751d] | 107 | outer_sum_F1 += GAUSS_W[i] * inner_sum_F1 * sin(theta); |
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| 108 | outer_sum_F2 += GAUSS_W[i] * inner_sum_F2 * sin(theta); |
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[deb7ee0] | 109 | } |
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[71b751d] | 110 | outer_sum_F1 *= 0.5*(v1b-v1a); |
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| 111 | outer_sum_F2 *= 0.5*(v1b-v1a); |
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[deb7ee0] | 112 | |
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| 113 | // Normalize as in Eqn. (15) without the volume factor (as cancels with (V*DelRho)^2 normalization) |
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| 114 | // The factor 2 is due to the different theta integration limit (pi/2 instead of pi) |
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[71b751d] | 115 | const double form_avg = outer_sum_F1/M_PI_2; |
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| 116 | const double form_squared_avg = outer_sum_F2/M_PI_2; |
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[deb7ee0] | 117 | |
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| 118 | // Multiply by contrast^2. Factor corresponding to volume^2 cancels with previous normalization. |
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[71b751d] | 119 | const double contrast = sld - solvent_sld; |
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[deb7ee0] | 120 | |
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| 121 | // Convert from [1e-12 A-1] to [cm-1] |
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[71b751d] | 122 | *F1 = 1.0e-2 * contrast * form_avg; |
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| 123 | *F2 = 1.0e-4 * contrast * contrast * form_squared_avg; |
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[deb7ee0] | 124 | } |
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[8de1477] | 125 | |
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[d86f0fc] | 126 | static double |
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| 127 | Iqabc(double qa, double qb, double qc, |
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[8de1477] | 128 | double sld, |
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| 129 | double solvent_sld, |
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| 130 | double length_a, |
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| 131 | double b2a_ratio, |
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| 132 | double c2a_ratio, |
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| 133 | double thickness) |
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| 134 | { |
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| 135 | const double length_b = length_a * b2a_ratio; |
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| 136 | const double length_c = length_a * c2a_ratio; |
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| 137 | const double a_half = 0.5 * length_a; |
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| 138 | const double b_half = 0.5 * length_b; |
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| 139 | const double c_half = 0.5 * length_c; |
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| 140 | const double vol_total = length_a * length_b * length_c; |
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| 141 | const double vol_core = 8.0 * (a_half-thickness) * (b_half-thickness) * (c_half-thickness); |
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| 142 | |
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| 143 | // Amplitude AP from eqn. (13) |
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| 144 | |
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| 145 | const double termA1 = sas_sinx_x(qa * a_half); |
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| 146 | const double termA2 = sas_sinx_x(qa * (a_half-thickness)); |
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| 147 | |
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| 148 | const double termB1 = sas_sinx_x(qb * b_half); |
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| 149 | const double termB2 = sas_sinx_x(qb * (b_half-thickness)); |
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| 150 | |
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| 151 | const double termC1 = sas_sinx_x(qc * c_half); |
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| 152 | const double termC2 = sas_sinx_x(qc * (c_half-thickness)); |
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| 153 | |
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| 154 | const double AP1 = vol_total * termA1 * termB1 * termC1; |
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| 155 | const double AP2 = vol_core * termA2 * termB2 * termC2; |
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| 156 | |
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| 157 | // Multiply by contrast^2. Factor corresponding to volume^2 cancels with previous normalization. |
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| 158 | const double delrho = sld - solvent_sld; |
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| 159 | |
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| 160 | // Convert from [1e-12 A-1] to [cm-1] |
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| 161 | return 1.0e-4 * square(delrho * (AP1-AP2)); |
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[71b751d] | 162 | } |
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