r""" This model fits the Porod function .. math:: I(q) = C/q^4 to the data directly without any need for linearisation (cf. Log I(q) vs Log q). Here $C = 2\pi (\Delta\rho)^2 S_v$ is the scale factor where $S_v$ is the specific surface area (ie, surface area / volume) of the sample, and $\Delta\rho$ is the contrast factor. For 2D data: The 2D scattering intensity is calculated in the same way as 1D, where the q vector is defined as .. math:: q = \sqrt{q_x^2+q_y^2} References ---------- .. [#] G Porod. *Kolloid Zeit*. 124 (1951) 83 .. [#] L A Feigin, D I Svergun, G W Taylor. *Structure Analysis by Small-Angle X-ray and Neutron Scattering*. Springer. (1987) Source ------ `porod.py `_ Authorship and Verification ---------------------------- * **Author:** * **Last Modified by:** * **Last Reviewed by:** * **Source added by :** Steve King **Date:** March 25, 2019 """ import numpy as np from numpy import inf, errstate name = "porod" title = "Porod function" description = """\ I(q) = scale/q^4 + background """ category = "shape-independent" parameters = [] def Iq(q): """ @param q: Input q-value """ with errstate(divide='ignore'): return q**-4 Iq.vectorized = True # Iq accepts an array of q values def random(): """Return a random parameter set for the model.""" sld, solvent = np.random.uniform(-0.5, 12, size=2) radius = 10**np.random.uniform(1, 4.7) Vf = 10**np.random.uniform(-3, -1) scale = 1e-4 * Vf * 2*np.pi*(sld-solvent)**2/(3*radius) pars = dict( scale=scale, ) return pars demo = dict(scale=1.5, background=0.5) tests = [ [{'scale': 0.00001, 'background':0.01}, 0.04, 3.916250], [{}, 0.0, inf], ]